Publications - AK Reactiondynamics

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Currently 2 manuscripts submitted and 3 in preparation

Mechanistic and Synthetic Investigations on the Dual Selenium--Acid/Photoredox Catalysis in the Context of the Aerobic Dehydrogenative Lactonization of Alkenoic Acids; Stefan Ortgies, R. Rieger, K. Rode, K. Koszinowski, J. Kind, Ch. M. Thiele, J. Rehbein, A. Breder, ACS Catal., 2017, 7, 7578.
21 Photoredox-induced radical 6-exo-trig cyclisations onto the indole nucleus: aromative versus dearomative pathways
Dirk Alpers, Malte Brasholz*, Julia Rehbein* Eur. J. Org. Chem. 2017, 15, 2186.

20 Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents
Michael Brown, Ravi Kumar, Julia Rehbein, Thomas Wirth*
Chem. Eur. J. 2016, 22, 4030–4035.

19 Chemistry in Motion - Off the MEP
J. Rehbein, B. Wulff  Tetrahedron Lett. 2015, 56, 6931.
18 Synthesis and Structural Analysis of DOTAZA (1,4,7,10-Tetra-azacyclododecane-1,4,7,10-tetra-azidoethylacetic acid) Complexes
Ella Kriemen, Malte Holzapfel, Erik Ruf, Julia Rehbein,Wolfgang Maison*
Eur. J. Inorg. Chem.
2015, 32, 5368–5378.
17 NHC-Catalyzed Benzoin Condensation – Is It All Down to the Breslow Intermediate?
Julia Rehbein*, Stephanie M. Ruser, Jenny Phan
Chem. Sci.
2015, 6, 6013–6018.
Studies towards the synthetic applicability of biocatalytic allylic oxidations with the lyophilisate of Pleurotus sapidus
Verena Weidmann, Serge Kliewer, Marco Sick, Sergej Bycinskij, Margarethe Kleczka, Julia Rehbein, Axel G. Griesbeck, Holger Zorn, Wolfgang Maison
Journal of Molecular Catalysis B: Enzymatic 2015, 121, 15–21.

15 Elucidation of the regio- and chemoselectivity of enzymatic allylic oxidations with Pleurotus sapidus - conversion of selected spirocyclic terpenoids and computational analysis
V. Weidmann, M. Schaffrath, H. Zorn, J. Rehbein, W. Maison Beilstein Journal of Organic Chemistry 2013, 9, 2233–2241 .

14 Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers from 1912 to 2012: 100 Years of Electrophilic Catalysis
Julia Rehbein, Martin Hiersemann
Synthesis 45, 1121-1159 (2013)

13 Novel Oxidative Rearrangements Using Hypervalent Iodine Reagents
Fateh V. Singh, Julia Rehbein, Thomas Wirth
Chemistry Open 1, 245-250 (2012)
12 Catalytic Asymmetric Gosteli-Claisen Rearrangement (CAGC)
Julia Rehbein, Martin Hiersemann -/- Herausgeber: Mathias Christmann, Stefan Bräse
Asymmetric Synthesis. More Methods and Applications 157-162 (2012), Verlag: Wiley-VCH, Weinheim

11 Total Synthesis of Natural and Non-Natural Δ5,6Δ12,13-Jatrophane Diterpenes and Their Evaluation as MDR Modulators
Christoph Schnabel, Katja Sterz, Henrik Müller, Julia Rehbein, Michael Wiese, Martin Hiersemann
Journal of Organic Chemistry 2011, 76, 512-522.
10 Integration of catalysis and analysis is the key: rapid and precise investigation of the catalytic asymmetric Gosteli-Claisen rearrangement
Johannes Troendlin, Julia Rehbein, Martin Hiersemann, Oliver Trapp Journal of the American Chemical Society 2011, 133, 16444-16450.
9 Gosteli-Claisen Rearrangement of Propargyl Vinyl Ethers: Cascading Molecular Rearrangements
Annika Gille, Julia Rehbein, Martin Hiersemann Organic Letters 2011, 13, 2122-2125.
8 Do we fully understand what controls chemical selectivity?
Julia Rehbein*, Barry K. Carpenter Physical Chemistry Chemical Physics 2011, 13, 20906-20922.

7 2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propanebis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
Julia Rehbein, Markus Schürmann, Hans Preut, Martin Hiersemann
Acta Crystallographica, Section E: Structure Reports Online E65, 2009, 737
Gosteli-Claisen Rearrangement: Substrate Synthesis, Simple Diastereoselectivity, and Kinetic Studies
Julia Rehbein, Sabine Leick, Martin Hiersemann Journal of Organic Chemistry 2009, 74, 1531–1540.
Gosteli-Claisen Rearrangement: DFT Study of Substituent-Rate Effects
Julia Rehbein, Martin Hiersemann Journal of Organic Chemistry 2009, 74, 4336–4342
Gosteli-Claisen Rearrangement: Rate Effects of Substituents, Solvents and Catalysts. A Combined Experimental and Theoretical Study
Julia Rehbein -/- Betreuer: Martin Hiersemann
Dissertation, Dortmund (2009)

3 Organocatalytic Claisen Rearrangement: Theory and Experiment
Martin Kirsten, Julia Rehbein, Martin Hiersemann, Thomas Strassner Journal of Organic Chemistry 2007, 72, 4001-4011.
2 Mechanistic aspects of the aliphatic Claisen rearrangement
Julia Rehbein, Martin Hiersemann -/- Herausgeber: Martin Hiersemann, Udo Nubbemeyer
The Claisen Rearrangement, Methods and Applications 2007, 525-557

1 Enantioselective synthesis of the C-14 to C-5 cyclopentane segment of jatrophane diterpenes
Hannes Helmboldt, Julia Rehbein, Martin Hiersemann
Tetrahedron Letters 2004, 45, 289-292.

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